1. 毕业设计（论文）的内容和要求
目标是总结钴催化C(sp3)-H键官能化的最新进展，可以对进一步开发新催化剂，导向基团和催化控制对映选择性的策略有所帮助。
2. 实验内容和要求
课题内容包含三个部分：低价钴催化的反应；Cp*Co(III)催化的反应；双齿导向基团辅助反应。
选择每个部分里具有代表的反应方程式来进行总结归纳以及具体的应用。
3. 参考文献
[1] selected general reviews on c-h bond functionalization: a) l. mcmurray, f. o''''hara, m. j. gaunt, chem. soc. rev. 2011, 40, 1885-1898; b) w. r. gutekunst, p. s. baran, chem. soc. rev. 2011, 40, 1976-1991; c) p. b. arockiam, c. bruneau, p. h. dixneuf, chem. rev. 2012, 112, 5879-5918; d) j. yamaguchi, a. d. yamaguchi, k. itami, angew. chem. 2012, 124, 9092-9142; angew. chem. int. ed. 2012, 51, 8960-9009; e) z. chen, b. wang, j. zhang, w. yu, z. liu, y. zhang, org. chem. front. 2015, 2, 1107-1295; f) t. gensch, m. n. hopkinson, f. glorius, j. wencel-delord, chem. soc. rev. 2016, 45, 2900-2936; g) r.-y. zhu, m. e. farmer, y.- q. chen, j.-q. yu, angew. chem. 2016, 128, 10734-10756; angew. chem. int. ed. 2016, 55, 10578-10599; h) j. r. hummel, j. a. boerth, j. a. ellman, chem. rev. 2017, 117, 9163-9227; i) c. g. newton, s.-g. wang, c. c. oliveira, n. cramer, chem. rev. 2017, 117, 8908-8976.
[2] reviews on cobalt-catalyzed c-h bond functionalization: a) k. gao, n. yoshikai, acc. chem. res. 2014, 47, 1208-1219; b) m. moselage, j. li, l. ackermann, acs catal. 2016, 6, 498-525; c) y. kommagalla, n. chatani, coord. chem. rev. 2017, 350, 117-135; d) m. usman, z.-h. ren, y.-y. wang, z.-h. guan, synthesis 2017, 49, 1419-1443; e) s. wang, s.-y. chen, x.-q. yu, chem. commun. 2017, 53, 3165-3180; f) t. yoshino, s. matsunaga, adv. synth. catal. 2017, 359, 1245-1262; g) t. yoshino, s. matsunaga, adv. organomet. chem. 2017, 68, 197-247; h) p. g. chirila, c. j. whiteoak, dalton trans. 2017, 46, 9721-9739.
[3] reviews on first-row metal-catalyzed c-h bond functionalization: a) a. a. kulkarni, o. daugulis, synthesis 2009, 4087-4109; b) e. nakamura, n. yoshikai, j. org. chem. 2010, 75, 6061-6067; c) y. nakao, chem. rec. 2011, 11, 242-251; d) l. c. m. castro, n. chatani, chem. lett. 2015, 44, 410-421; e) j. miao, h. ge, eur. j. org. chem. 2015, 7859-7868; f) b. su, z.-c. cao, z.-j. shi, acc. chem. res. 2015, 48, 886-896; g) w. liu, l. ackermann, acs catal. 2016, 6, 3743-3752; h) w.-h. rao, b.-f. shi, org. chem. front. 2016, 3, 1028-1047; i) g. pototschnig, n. maulide, m. schnürch, chem. eur. j. 2017, 23, 9206-9232; j) r. shang, l. ilies, e. nakamura, chem. rev. 2017, 117, 9086-9139. k) y. hu, b. zhou, c. wang, acc. chem. res. 2018, 51, 516-827; l) n. rajesh, n. barsu, b. sundararaju, tetrahedron lett. 2018, 59, 862-868.
4. 毕业设计（论文）计划
1. 资料搜集：2022年12月23日-2022年02月23日2. 写作初稿：2022年02月24日-2022年03月31日3. 修改提高：2022年04月01日-2022年04月30日4. 打印上交：2022年05月01日-2022年05月05日
