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Chapter3 Exhaust Emission and Control |
第三章 尾气排放与控制 |
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Marine engine designers in recent years have had to address the challenge of tightening controls on noxious exhaust gas emissions imposed by regional, national and international authorities responding to concern over atmospheric pollution. Exhaust gas emissions from marine diesel engines largely comprise nitrogen, oxygen, carbon dioxide and water vapour, with smaller quantities of carbon monoxide, oxides of sulphur and nitrogen, partially reacted and non-combusted hydrocarbons and particulate material (Figures 3.1 and 3.2). Nitrogen oxides (NOx)—generated thermally from nitrogen and oxygen at high combustion temperatures in the cylinder—are of special concern since they are believed to be carcinogenic and contribute to photochemical smog formation over cities and acid rain (and hence excess acidification of the soil). Internal combustion engines primarily generate nitrogen oxide but less than 10 per cent of that oxidizes to nitrogen dioxide the moment it escapes as exhaust gas. Sulphur oxides (SOx)—produced by oxidation of the sulphur in the fuel—have an unpleasant odour, irritate the mucus membrane and are a major source of acid rain (reacting with water to form sulphurous acid). Acid deposition is a trans-boundary pollution problem: once emitted, SOx can be carried over hundreds of miles in the atmosphere before being deposited in lakes and streams, reducing their alkalinity. Sulphur deposition can also lead to increased sulphate levels in soils, fostering the formation of insoluble aluminium phosphates which can cause a phosphorous deficiency. Groundwater acidification has been observed in many areas of Europe; this can lead to corrosion of drinking water supply systems and health hazards due to dissolved metals in those systems. Forest soils can also become contaminated with higher than normal levels of toxic metals, and historic buildings and monuments damaged. Hydrocarbons (HC)—created by the incomplete combustion of fuel and lube oil, and the evaporation of fuel—have an unpleasant odour, are partially carcinogenic, smog forming and irritate the mucus membrane (emissions, however, are typically low for modern diesel engines). Carbon monoxide (CO)—resulting from incomplete combustion due to a local shortage of air and the dissociation of carbon dioxide— is highly toxic but only in high concentrations. Particulate matter (PM) is a complex mixture of inorganic and organic compounds resulting from incomplete combustion, partly unburned lube oil, thermal splitting of HC from the fuel and lube oil, ash in the fuel and lube oil, sulphates and water. More than half of the total particulate mass is soot (inorganic carbonaceous particles), whose visible evidence is smoke. Soot particles (unburned elemental carbon) are not themselves toxic but they can cause the build-up of aqueous hydrocarbons, and some of them are believed to be carcinogens. Particulates constitute no more than around 0.003 per cent of the engine exhaust gases. Noxious emissions amount to 0.25-0.4 per cent by volume of the exhaust gas, depending on the amount of sulphur in the fuel and its lower heat value, and the engine type, speed and efficiency. Some idea of the actual pollutants generated is provided by MAN Bamp;W Diesel, which cites an 18 V 48/60 medium speed engine in NOx optimized form running at full load on a typical heavy fuel oil with 4 per cent sulphur content. A total of approximately 460 kg of harmful compounds are emitted per hour out of around 136 tonnes of exhaust gas mass per hour. Of the 0.35 per cent of the exhaust gas formed by pollutants, NOx contributes 0.17 per cent, sulphur dioxide 0.15 per cent, hydrocarbons 0.02 per cent, carbon monoxide 0.007 per cent and soot/ash 0.003 per cent. Carbon dioxide: some 6 per cent of the exhaust gas emissions from this engine is carbon dioxide. Although not itself toxic, carbon dioxide contributes to the greenhouse effect (global warming) and hence to changes in the Earthrsquo;s atmosphere. The gas is an inevitable product of combustion of all fossil fuels, but emissions from diesel engines—thanks to their thermal efficiency—are the lowest of all heat engines. A lower fuel consumption translates to reduced carbon dioxide emissions since the amount produced is directly proportional to the volume of fuel used, and therefore to the engine or plant efficiency. As a rough guide, burning one tonne of diesel fuel produces approximately three tonnes of carbon dioxide. International concern over the atmospheric effect of carbon dioxide has stimulated measures and plans to curb the growth of such emissions, and the marine industry must be prepared for future legislation. (A switch from other transport modes—air, road and rail—to shipping would nevertheless yield a substantial overall reduction in emissions of the greenhouse gas because of the higher efficiency of diesel engines.) The scope for improvement by raising the already high efficiency level of modern diesel engines is limited and other routes have to be pursued: operating the engines at a fuel-saving service point; using marine diesel oil or gas oil instead of low sulphur heavy fuel oil; adopting diesel-electric propulsion (the engines can be run continuously at the highest efficiency); or exploiting a diesel combined cycle incorporating a steam turbine. The steam-injected diesel engine is also promising. Compared with land-based power installations, fuel burned by much of shipping has a very high sulphur content (up to 4.5 per cent and more) and contributes significantly to the overall amount of global emissions at sea and in port areas. Studies on sulphur pollution showed that in 1990 SOx emissions from ships contributed around 4 per cent to the total in Europe. In 2001 such emissions represented 剩余内容已隐藏,支付完成后下载完整资料 资料编号:[153123],资料为PDF文档或Word文档,PDF文档可免费转换为Word |
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